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PRIONE

TRUE INNOVATION
SEAWATER BATTERY

Setting a New Standard for Next-Generation Energy Storage with Seawater Battery Cells,
Composite Separators, and High-Performance Anode Materials.

Technology

High-functionality materials that determine battery performance

  • Seawater Battery

    Seawater battery

  • PLP

    Plasma in Liquid Process

  • TMI-Zero Method

    Transition Metal Impurities

PLP

Plasma in Liquid Process

  • Plasma generated
    within a solution
  • Simple device configuration
  • Nanomaterial synthesis through
    decomposition and recombination
    of the solution and electrode materials
  • Platform Process
Seawater Battery

Seawater battery

  • CHARGING/
    DISCHARGING
  • KEY ADVANTAGES
  • Pouch Cell
TMI-Zero Method

Transition Metal Impuritie

  • World's FirstPurification-free Process
  • World's FirstCatalyst Impurities 0 ppm
  • Low-temperature Process (under 600°C)
  • Low-cost Eco-friendly Process

Plasma generated within a solution

Plasma generated within a solution at room temperature and atmospheric pressure

PLP process generating plasma within a solution at room temperature and atmospheric pressure

Simple device configuration

Composed only of a power source, electrodes, solution, and reactor

PLP device composed only of a power source, electrodes, solution, and reactor - synthesis of Tin-Conductive additive, SIB anode, Si-Conductive additive

Nanomaterial synthesis through
decomposition and recombination of the solution and electrode materials

Synthesis of various nanomaterials through the decomposition and recombination
of all solvents, solutes, and the electrode wire required to generate plasma

  • ex. Synthesis of platinum nanoparticles by
    reducing platinum ions dissolved in the solution
    with hydrogen radicals generated in the plasma
  • ex. Synthesis of carbon nanomaterials through
    decomposition and recombination of organic solvents
  • ex. Easy synthesis of metal nanoparticles
    by sputtering of the electrode wire

Platform Process

A Platform Process capable of synthesizing various materials with a single PLP process

Synthesis of
Carbon
Nanomaterials

  • Carbon black, Heteroatom doped carbon black
  • Carbon nano sheet, Heteroatom doped carbon nano sheet

Synthesis of
Metal
Nanomaterials

  • Synthesis of metal nanoparticles and metal nano ink by
    plasma reduction of any metal that can exist as ions in a solution
  • Synthesis of metal nanoparticles and metal nano ink by
    sputtering of any metal that can be formed into an electrode wire

Synthesis of
Carbon-Metal
Nano Composites

  • Synthesis of carbon materials with
    metal nanoparticles supported or encapsulated

Surface Treatment
of Carbon Materials

  • Dispersion treatment by functional group
    modification on the surface of carbon materials such as CNT

CHARGING / DISCHARGING

A device that stores electrical energy using seawater as the electrolyte,
utilizing the sodium ions (Na+) in seawater and water

CHARGING

  • Utilizes sodium in seawater during charging
  • OH- (hydroxide ions) in the seawater produce O2 and H2O,
    separating electrons (e-) (OER)
  • The generated sodium ions move to the anode through the electrolyte
  • Electrons (e-) move through the installed wire

DISCHARGING

  • Oxidation occurs at the sodium in the anode,
    generating ions (Na+) and electrons (e-)
  • Sodium ions (Na+) move to the cathode (seawater) through the electrolyte
  • Electrons (e-) move to the cathode through the circuit, forming a current
  • At the cathode, sodium ions (Na+),
    electrons (e-), dissolved oxygen (O2) in seawater, and
    H2O combine to produce sodium hydroxide (NaOH) (ORR)

KEY ADVANTAGES

  • Eco-friendly

    Seawater-based, minimizing environmental pollution

  • Low-cost

    Replaces rare metals, reducing costs

  • High Safety

    Low risk of fire and explosion

  • Large-capacity Storage

    Capable of long-term, large-scale energy storage

Pouch Cell

Pouch cell exploded view - Pouch, Activated Carbon, Flexible separator, MEA, SWB anode, Insulator
  • 2nd-generation Polymer Separator

    Requires a FLEXIBLE polymer composite material that is easily deformable and allows for various designs

  • Anode Material for Seawater Battery

    Anode material for seawater batteries with high capacity and long-term stability - maximizing energy storage and seawater desalination capabilities

  • Double-sided Electrode Structure

    Maximizes energy storage capacity by utilizing both sides of the electrode as active layers

  • Increased Productivity

    Enables rapid product manufacturing by adopting Roll to Roll technology

  • Uniform Thickness

    Maintains a uniform material thickness with constant pressure

  • Continuous Processing

    Enables continuous processing using rolls, optimized for mass production

  • Increased Bonding Strength

    Forms strong bonding through compression when joining multiple layers of material

World's First

Purification-free Process

  • The PRIONE process does not use transition metal catalysts
    such as Fe, Co, Ni, and Mo

  • Intellectual property rights for catalyst purification
    are no longer required

  • As a purification-free process,
    a high-temperature reactor using halogen gas
    for catalyst purification is not required

  • High-concentration acid treatment is also not required,
    so no environmental costs are incurred

  • Since no purification is performed,
    no chemical or structural damage
    occurs to the synthesized CNT

World's First

Catalyst Impurities 0 ppm

  • Since no transition metal catalyst is used,
    the impurity content from the catalyst is 0 ppm

  • 0 ppm

    PRIONE's special catalyst can be removed
    to 0 ppm during the process

  • When used as a conductive additive for batteries,
    the more PRIONE's special catalyst remains as residue,
    the more it greatly contributes to improving battery performance

Under 600°C

Low-temperature Process

  • The advantage of the low-temperature process is
    low cost due to low power consumption

  • The temperature gradient in the reaction zone is not large,
    enabling production of uniform quality

  • When doping hetero atoms such as nitrogen,
    because it is a low-temperature process, the doping amount can be greatly increased compared to high-temperature processes,
    enabling the manufacture of high-functionality CNT

Low-cost Eco-friendly Process

  • PRIONE's catalyst is very inexpensive, with a precursor price 1/20 that of Ferrocene,
    the common CNT catalyst (based on Sigma Aldrich)

  • No additional expensive chemicals such as Thiophene
    used in conventional CNT processes are needed;
    only PRIONE's catalyst and a carbon precursor are required

  • The carbon precursor also uses a very low-cost precursor,
    greatly reducing overall production costs, and the reaction temperature is
    much lower than typical CNT synthesis temperatures, so less production power is consumed

  • Since the purification process is omitted, no purification costs are incurred,
    and therefore no environmental costs are incurred

Materials

High-functionality materials that determine battery performance

  • Organic-Inorganic Composite Separator

    Enhanced Safety

  • SIB Anode

    High Performance

  • Carbon Nano Tube

    High Conductivity

  • Nano Silicon

    High Capacity

Materials

Hybrid Membrane

  • Limitations of Conventional
    NASICON Separators

    Low mechanical stability

    Limited electrochemical performance

    Next-generation separator technology required
  • Performance Improvement Points
    Thickness reduced to about 80%

    Improved flexibility

    Reduced stack resistance

    Enhanced battery efficiency
  • Core Technology Elements

    Maintains Na⁺ selectivity during charging

    Higher performance than before
    with improved stability

  • Technical Significance

    Overcomes the structural and performance limits of first-generation separators

    Na⁺ selectivity + stability

    Improved productivity and applicable to
    next-generation seawater batteries

Conventional (1st Gen) Seawater Battery

2nd Gen Seawater Battery

Hybrid Membrane

  • 80% thickness reduction compared to conventional separators
  • Reduced resistance and secured homogeneity at the electrode-catalyst junction
  • Minimized interfacial resistance
  • Separator Durability

    Brittle
    Low durability

    Flexible
    Various forms

  • Mass Production of Cells

    Brittle
    Continuous process impossible

    Flexible
    Continuous process possible
    (Roll to Roll)

  • Applicability to Various Cell Structures

    Brittle
    Fixed form

    Flexible
    Various forms

  • Poor Bonding with Pouch or Case

    Ceramic material
    Low adhesion to pouch

    Polymer material
    High adhesion to pouch

Development of proprietary organic-inorganic composite separator technology that blocks water movement within the cathode while enabling selective Na⁺ transport

Hybrid Membrane

  • Minimizes the sodium-ion pathway through MEA integration
  • Lowers cell resistance and enhances performance and stability
  • Introduction of Roll to Roll enables continuous and rapid product manufacturing
  • Maintains uniform thickness under constant pressure, thereby securing stable performance

MEA & Cell Structure

Double-side electrode structure

High energy density achieved using a double-side electrode structure

Bonding and sealing structure between pouch film and separator

PRIONE's unique bonding and sealing structure that blocks moisture penetration

PBA Surface Technology

SURFACE MODIFICATION OF PRUSSIAN BLUE ANALOGUE (PBA) NANOPARTICLES

Na⁺ selectivity and ionic conductivity are controlled through the porous lattice structure and surface modification of PBA.

PBA Surface Technology

NASICON + Porous Cathode

NASICON Porous Cathode

PBA Membrane + Porous Cathode

PBA Membrane Porous Cathode

  • Selective Na⁺ Transport
  • Fast Ion Path
  • Low Interfacial Resistance

Performance Comparison

  • High specific surface area gives strong
    output characteristics, suitable for ESS

  • Excellent power efficiency thanks to
    high capacity and long-term life stability

  • Capacity retention at high current density and
    outstanding stability enable use in
    a wide range of applications

  • Comparison with Hard Carbon used in first-generation seawater batteries
  • Using the developed PRIONE anode material improves the shortcomings of the Hard Carbon used in first-generation seawater batteries (low output characteristics and capacity)
  • Replacing the NASICON separator used in first-generation seawater batteries with the polymer separator under development provides high ionic conductivity while reinforcing the physical strength that becomes an issue during mass production
Materials

Performance Advantages

  • High Specific Surface Area

    Secures abundant active reaction area to
    deliver excellent electrochemical performance.

  • Stable Charge/Discharge Characteristics

    High initial coulombic efficiency (ICE) and
    excellent cycle characteristics
    maintain stable long-term battery performance.

  • Excellent Pore Structure

    Uniform pore distribution facilitates Na⁺
    ion transport, enabling fast
    charge/discharge and high output characteristics.

  • Application to Next-Generation Sodium-ion Batteries

    Applicable to a wide range of Sodium-ion Battery
    fields such as ESS, power storage systems, and
    industrial energy storage devices.

Standard
Carbon black

An anode material based on standard Carbon black, providing excellent electrochemical characteristics and
stable charge/discharge performance.
A standard product line applicable to various Sodium-ion Battery systems

  • Stable Cycle Performance
  • High Carbon Purity
  • Optimized Particle Size
High Capacity
SIB Anode

An anode material achieving high capacity of about 650mAh/g and higher energy density
Suitable for next-generation Sodium-ion Batteries required for high-performance electronics that use LIB.

  • High Capacity
  • Optimized Carbon Structure
  • Long Cycle Life

Using the PLP process, hetero atoms are easily and uniformly doped, achieving a higher surface area than competitors

Performance Comparison

Compared to Hard Carbon (320 mAh/g at 1C), the PRIONE anode material (695 mAh/g at 3C) exhibits more than twice the irreversible capacity. In addition, the initial coulombic efficiency (ICE) is about 92-93%, and it maintains a high capacity of about 550 mAh/g even at a high rate of 5C.

Performance Comparison

When manufacturing a sodium-ion battery cell with the PRIONE anode of about 550 mAh/g capacity,
the reduced anode loading improves energy density by about 8% (≈15 Wh/kg)

  • Higher Energy Density

    About 8% improvement at the same voltage

    Stores more energy in a smaller volume

  • Reduced Anode Loading

    Less anode used while maintaining the same capacity

    Reduced overall cell weight and volume

  • Improved Battery Performance

    Increased charge/discharge efficiency

    Enhanced system efficiency and competitiveness

Materials

CNT

CNT

Carbon Nano Tube
  • EDS mapping confirms good dispersion of Silicon and C
  • Applying this composite as a conductive additive can maximize efficiency
  • A new material currently gaining attention across various industries, with excellent mechanical properties, electrical selectivity, field emission characteristics, and high-efficiency hydrogen storage medium properties

CNT

CNT

Low-cost Carbon Nano Tube (CNT) manufacturing technology using alkali metals

Conventional CNT Manufacturing Technology
  • Uses organometallic compounds such as Fe, Ni, and Co as catalyst metals

    Limited reserves lead to high costs
    (around $14,000/ton for Ni)

  • Requires an acid treatment process using acid solutions such as sulfuric acid and nitric acid

    Issues with work safety, treatment of pollutants,
    and high costs

Developed CNT Manufacturing Technology
  • Uses water-soluble alkali metals (Na, K, etc.) as catalyst metals

    Low cost and infinitely extractable from seawater
    (around $150/ton for Na)

  • No acid treatment process required, reducing process cost

    Enables 'high value-added' CNT manufacturing

CNT

Target Technology (Technical Merit)
  • A sodium chloride aqueous solution is applied to form nanoparticles, which are then
    sprayed into a high-temperature heat-treatment reactor to grow continuous MWCNTs.
    The absence of transition metals provides stability against explosion, fire, and the like
  • An innovative process that overcomes the key drawbacks of the fluidized-bed reaction method, currently the main mass-production technique, such as expensive reducing agents,
    and the high-cost, discontinuous manufacturing process caused by support loading and removal.
    Low damage to the product results in excellent performance

CNT

  • Active material amount , battery capacity
  • 5x the energy density of carbon black, over 10% higher conductivity
  • Reduced battery charging time
Materials

Silicon

TEM image of the
synthesized material

EDS mapping of the
synthesized material

Silicon

  • High performance: high purity and small particle size
  • Typical Nano Si Powder: average particle size of 50-100nm
  • PRIONE Nano Si Powder: average particle size of 20nm or less

Value

Sustainable
Energy
Innovation

Driving Innovation for Sustainable Energy

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PRIONE
Sustainable Energy
Next-Generation Energy Storage
Technology Utilizing Seawater
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Advanced Materials
Advanced Materials
for Enhanced Performance
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Integrated Technology
Integrated Technology
from Materials to Cells
PRIONE
Sustainable Energy
Next-Generation Energy Storage
Technology Utilizing Seawater
PRIONE
Advanced Materials
Advanced Materials
for Enhanced Performance
PRIONE
Integrated Technology
Integrated Technology
from Materials to Cells
FROM SEAWATER TO ENERGY

How Seawater Becomes Energy

  • SeawaterSodium Ions in Seawater
  • Ion SeparationSelective Ion Separation
  • Ion TransferIon Transport & Storage
  • Energy StorageElectrical Energy Storage
  • PowerApplications Across
    Diverse Industries

Business

ADVANCED
ENERGY
SOLUTIONS

Next-Generation Energy
Solutions Driven by
Materials Technology

MORE
  • Seawater batteryNext-Generation Energy Storage
    Powered by Seawater
  • SIB AnodeHigh-Capacity Anode Material for Sodium-Ion
    Batteries with Long Cycle Life
  • Conductive AdditiveHigh-performance composite separator with
    excellent thermal stability and ion conductivity.
BEST VALUE INNOVATION BEST VALUE INNOVATION BEST VALUE INNOVATION

Patents & projects

The Strength of PRIONE Built
on Research & Technology

Leveraging proprietary material technologies and patented innovations,
we accelerate the commercialization of next-generation energy technologies through a wide range of national R&D projects.

MORE
PRIONE

Patent Portfolio

15Patents
PRIONE

National R&D Projects

13R&D
Projects

Support

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